Constellation, le dépôt institutionnel de l'Université du Québec à Chicoutimi

Résumé

In this article, two synthetic esters along with a natural ester are investigated to monitor the generation of colloidal and dissolved decay particles under thermal aging. The thermal aging of the oils is carried out as per a modified ASTM D1934 in the presence of cellulose and copper at elevated temperatures. Later, the colloidal and dissolved decay particles are monitored as per ASTM D1698 (centrifuge treatment) and ASTM D7150 (Fuller's earth filtration), respectively. The aged and treated dielectric liquids are characterized for the number of decay particles, oil absorbance curves, the concentration of dissolved decay content, and turbidity as per ASTM standards. The evolution of colloidal and dissolved decay contents is individually reported for ester fluids and mineral oils. The degradation in mineral oils has been witnessed by both dissolved and colloidal particles. The generation of colloidal particles following the degradation of ester fluids is almost negligible, whereas dissolved decay content is noticed with thermal degradation time. Importantly, the obtained results depict the ability of esters to dissolve more sludge. This is due to the high (oxidative) stability of ester leading to reduced radical decomposition products. Also, the temperature solvent nature of the ester group tends to dissolve sludge particles back to the liquid phase into the bulk liquid.