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Surface degradation of CeO2 stabilized acrylic polyurethane coated thermally treated jack pine during accelerated weathering

Saha Sudeshna, Kocaefe Duygu, Boluk Yaman et Pichette André. (2013). Surface degradation of CeO2 stabilized acrylic polyurethane coated thermally treated jack pine during accelerated weathering. Applied Surface Science, 276, p. 86-94.

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URL officielle: https://doi.org/10.1016/j.apsusc.2013.03.031

Résumé

The thermally treated wood is a new value-added product and is very important for the diversification of forestry products. It drew the attention of consumers due to its attractive dark brown color. However, it loses its color when exposed to outside environment. Therefore, development of a protective coating for this value added product is necessary. In the present study, the efficiency of CeO2 nano particles alone or in combination with lignin stabilizer and/or bark extracts in acrylic polyurethane polymer was investigated by performing an accelerated weathering test. The color measurement results after accelerated weathering demonstrated that the coating containing CeO2 nano particles was the most effective whereas visual assessment suggested the coating containing CeO2 nano particles and lignin stabilizer as the most effective coating. The surface polarity changed for all the coatings during weathering and increase in contact angle after weathering suggested cross linking and reorientation of the polymer chain during weathering. The surface chemistry altered during weathering was evaluated by ATR-FTIR analysis. It suggested formation of different carbonyl byproducts during weathering. The chain scission reactions of the urethane linkages were not found to be significant during weathering.

Type de document:Article publié dans une revue avec comité d'évaluation
Volume:276
Pages:p. 86-94
Version évaluée par les pairs:Oui
Date:2013
Sujets:Sciences naturelles et génie > Génie > Génie des matériaux et génie métallurgique
Département, module, service et unité de recherche:Départements et modules > Département des sciences appliquées > Module d'ingénierie
Mots-clés:Surface degradation, thermally treated jack pine, acrylic polyurethane, accelerated weathering, CeO2 nano particles, color change, wetting, ATR-FT-IR analysis
Déposé le:21 févr. 2019 22:50
Dernière modification:01 mars 2019 01:59
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